I was looking at the cache scales you set:
If these are the scales you are going with, I would recommend that you set you visible ranges for the layers in ArcMap so that the caching scale is in the middle of the layer visibility range in ArcMap. Example:
1:15,000,000 - 1:6,500,001
1:6.500,000 - 1:2,000,001
1:2,000,000 - 900,001
1:900,000 - 1:650,001
1:650,000 - 1:400,001
1:400,000 - 1:175,001
1:175,000 - none