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KML layer is not a supported data format for the ArcGIS for Smartphone/Tablet application including Android platform and iOS platforms at this time. KML support is available at version 2.2 of ArcGIS for Windows Phone App. I suggest posting this feature enhancement to 'support KML layer on Android OS platform' on ArcGIS Ideas. The ArcGIS Ideas is a submission portal which lets our customers get involved. You can suggest new products, promote favorite enhancements and interact with ESRI Teams.